Hydrophobic Hydration of the Hydrocarbon Adamantane in Amorphous Ice

نویسندگان

چکیده

Hydrophobic molecules are by definition difficult to hydrate. Previous studies in the area of hydrophobic hydration have therefore often relied on using amphiphilic where hydrophilic part a...

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Hydrophobic hydration in cyclodextrin complexation.

We report temperature-dependent acoustic and densimetric data on changes in volume, expansibility, and adiabatic compressibility accompanying the binding of 1-adamantanecarboxylic acid (AD) to beta-cyclodextrin (beta-CD). We interpret our volumetric results in terms of hydration. Based on our compressibility and expansibility data, we estimate that, at 25 degrees C, the binding of AD to beta-CD...

متن کامل

Solutes probe hydration in specific association of cyclodextrin and adamantane.

Using microcalorimetry, we follow changes in the association free energy of beta-cyclodextrin (CD) with the hydrophobic part of adamantane carboxylate (AD) due to added salt or polar (net-neutral) solutes that are excluded from the molecular interacting surfaces. Changes in binding constants with solution osmotic pressure (water activity) translate into changes in the preferential hydration upo...

متن کامل

Hydration of hydrophobic biological porphyrins.

Explicit solvent, single solute molecular dynamics simulations of protoporphyrin IX and its Fe(2+) complex (heme) in water were performed. The relation of solute-solvent was examined through the spatial distribution functions of water molecules around the centroid of the porphyrin ring. A detailed description of the time-averaged structure of water surrounding the solutes as well as of its fluc...

متن کامل

Hydration of the HCl and NH3 molecules adsorbed on amorphous water–ice surface

The interactions between HCl and NH3 molecules adsorbed on amorphous solid water (ASW) have been investigated by temperature-programmed time-of-flight secondary ion mass spectrometry (TP-TOF-SIMS). The NH4 þ ion is sputtered predominantly from codeposited HCl and NH3 molecules on ASW due to collision-induced proton transfer reactions. The NH4 þ yield is enhanced above 60 K as a consequence of t...

متن کامل

the effect of the record infancy in crimilly acts of guilties (in karaj city)

چکیده یکی از مهمترین دغدغه های بزرگ جوامع بشری، از دیر باز تا کنون که ذهن پژوهشگران و متخصصان بهداشت روانی و اجتماعی و دولتها رابه خود مشغول داشته، مسأله ی بزهکاری می باشد. شناخت کامل پدیده ی بزهکاری و بزهکار، علل وعوامل سقوط یک انسان، چگونگی درمان وی و درنهایت پیشگیری ازبزهکاری ودریک کلام سالم سازی یک جامعه، رسالت عظیم، انسانی ومقدسی می باشد که با بررسی شخصیت مجرم یعنی[ انسانی که تحت شرای...

15 صفحه اول

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Faraday Discussions

سال: 2023

ISSN: ['1359-6640', '1364-5498']

DOI: https://doi.org/10.1039/d3fd00102d